TEXACO REFINING AND MARKETING INC -- 00423 TEXACO LOW SULFUR DIESEL 1 -- 9140-00-000-0185
===================== Product Identification ===================== Product ID:00423 TEXACO LOW SULFUR DIESEL 1 MSDS Date:09/02/1993 FSC:9140 NIIN:00-000-0185 === Responsible Party === Company Name:TEXACO REFINING AND MARKETING INC Address:1111 RUSK ST Box:1404 City:HOUSTON State:TX ZIP:77002-3310 Country:US Info Phone Num:914-838-7204/7336 Emergency Phone Num:914-831-3400 800-424-9300(CHEMTREC) Preparer's Name:MANAGER,PRODUCT SAFETY CAGE:38341 === Contractor Identification === Company Name:MARIS CRANE AND HOIST CO INC (CAGE CANCELLED) Box:City:PHILADELPHIA State:PA ZIP:19092 Country:US Phone:NONE CAGE:38341 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETROLEUM SOLVENT CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED Ingred Name:CUMENE (SARA III) <240PPM CAS:98-82-8 RTECS #:GR8575000 Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 0-0.01% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 RAT IS >25MG/KG(SIMILAR PROD) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.MAY BE DERMALLY ABSORBED IN HARMFUL AMOUNTS(LD50 DERMAL RABBIT >3G/KG).INGEST:MAY CAUSE GI TRACT IRRITATION.MAY CAUSE LUNG DAMAGE IF VOMITED AFTER I NGESTING.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND CNS EFFECTS.CHRONIC:MAY CAUSE DERMATITIS OR SKIN CANCER. Explanation of Carcinogenicity:BENZENE CAUSES LEUKEMIA.MIDDLE DISTILLATE CAN PRODUCE SKIN CANCER.WHOLE DIESEL EXHAUST IS A POTENTIAL CARCINOGEN. Effects of Overexposure:EYES:REDNESS.SKIN:REDNESS,SWELLING.INHAL:HEADACHE,NAUS EA,VOMITING,DIZZINESS,DROWSINESS,EUPHORIA,LOSS OF COORDINATION.INGEST:NAUSEA,VOMITING,DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:GET PROMPT QUALIFIED ME DICAL ATTENTION.INDUCE VOMITING ONLY! UNDER THE ADVICE OF A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>115F,>46C Autoignition Temp:Autoignition Temp Text:410F Lower Limits:0.7 Upper Limits:5.0 Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE,FOAM.WATER OR FOAM MAY CAUSE FROTHING. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID.FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SHUT OFF LEAK IF SAFE.DIKE.SOAK UP WITH A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER CONTAINER FOR DISPOSA L.AVOID DISCHARGE TO SEWER. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED AREA FOR COMBUSTIBLE MATERIALS.KEEP CONTAINER CLOSED WHEN NOT IN USE.AVOID HEAT AND SOURCES OF IGNITION. Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE;DISPOSE OF PROPERLY.GROUND CONTAINERS WHEN TRANSFERRING LIQUIDS;FLOWING HYDROCARBONS CAN BECOME ELECTROSTATICALLY CHARGED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NOISH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS,DEPENDING ON THE AIRBORN CONCENTRA TION. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Protective Gloves:NITRILE Eye Protection:CHEMICAL SPLASH GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health HMIS(LEVIEN) NOTES THAT THERE IS AN EXISTING RECORD USING CAGE-3B431.HMIS BELIEVES THIS CAGE CODE TO BE IN ERROR. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:304-574F Vapor Pres:<710 Spec Gravity:.816 Viscosity:1.3-2CST@100F Appearance and Odor:LIQUID;CLEAR TO PALE YELLOW;TYPICAL FUEL OIL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,IRRITATING ALDEHYDES AND KETONES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.RCRA CODE FOR BENZENE IS U019. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.